Tuning Luminescence Of Didysprosium Single-Molecule Magnets With A Pi-Conjugated/Non-Conjugated Bridging Ligand
DALTON TRANSACTIONS(2021)
Abstract
Herein, we reported two didysprosium single-molecule magnets constructed with {Dy(bbpen)(MeOH)} subunits and a pi-conjugated tpb or non-conjugated tpcb bridging ligand. The former exhibits extremely weak luminescence that makes it difficult to simulate its emission spectra. However, the later shows obviously enhanced and well-resolved luminescence, which helps us to gain knowledge about the magneto-optical correlation and the relevant magnetic energy levels.
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Key words
luminescence,bridging ligand,single-molecule,non-conjugated
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