Synthesis And Thermal Behavior Of Heteroleptic Gamma-Substituted Acetylacetonate-Alkoxides Of Titanium

Diane Bijou,Thibaut Cornier,Shashank Mishra,Lynda Merzoud,Henry Chermette,Erwann Jeanneau,William Maudez,Giacomo Benvenuti,Stephane Daniele

European Journal of Inorganic Chemistry（2021）

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摘要

A series of heteroleptic titanium derivatives of general formula [Ti(OiPr)(2)(R-acac)(2)] with acetylacetonate ligands modified in the internal (gamma- or 3-) position by different substituents (R=OAc, NO2, Me, Et, Cl, Br) has been synthesized and completely characterized by liquid multinuclear NMR and FTIR. The influence of the nature of the group on the thermal stability of the different complexes was studied by thermogravimetric analysis (TGA) and gave the following decreasing stability ranking: H更多

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关键词

Density functional calculations, &#946, -Diketonates, Ligand design, Thermal behavior, Titanium

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