The Reactivity Of Multidentate Schiff Base Ligands Derived From Bi- And Terphenyl Polyamines Towards M(Ii) (M=Ni, Cu, Zn, Cd) And M(Iii) (M=Co, Y, Lu)

Multidentate Schiff base ligands derived from a selection of biphenyl- and terphenyl polyamines were synthesized, and their reactivity towards divalent (Ni, Cu, Zn, Cd) and trivalent (Co, Y, Lu) metals was studied by single-crystal X-ray diffraction analysis, NMR spectroscopy, and UV/Vis spectroscopy for the Cu(II) complexes. Large variations in the resulting complexes were observed based on the relative position of the amine substituents in the parent triamines, as well as the electronic properties of the Schiff base ligand itself. Most notably, Schiff base ligands derived from a m-terphenyl-2,2',2''-triamine were found to coordinate in a tetradentate, pentadentate or hexadentate fashion, depending on the size and the valency of the corresponding metal center.