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Lone-Pair-Induced Structural Ordering in the Mixed-Valent 0D Metal-Halides Rb23BiIIIxSbIII7–xSbV2Cl54 (0 ≤ x ≤ 7)

Bogdan M. Benin,Kyle M. McCall,Michael Wörle,Dominique Borgeaud,Thomas Vonderach,Kostiantyn Sakhatskyi,Sergii Yakunin,Detlef Günther,Maksym V. Kovalenko

Chemistry of Materials（2021）

Cited 5|Views7
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Abstract
Mixed-valent metal-halides containing ns2 lone pairs may exhibit intense visible absorption, while zero-dimensional (0D) ns2-based metal-chlorides are generally colorless but have demonstrated prom...
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