Single Crystal To Single Crystal Transformation Of Spin-Crossover Coordination Polymers From 3d Frameworks To 2d Layers

Yu Gong,Wang-Kang Han,Hui-Shu Lu,Qing-Tao Hu, Huan Tu, Pei-Ni Li,Xiaodong Yan,Zhi-Guo Gu

JOURNAL OF MATERIALS CHEMISTRY C（2021）

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摘要

A ligand exchange induced single crystal to single crystal (SCSC) transformation from 3D Hofmann-type frameworks [Fe(ep)M(CN)(4)] (ep = ethylpyrazine; M = Pt, Pd) to 2D layer networks [Fe(mp)(2)M(CN)(4)] (mp = methoxypyrazine) was observed. Interestingly, the different pillar-ligands showed a significant influence on the structural assembly and spin-crossover properties.

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关键词

single crystal transformation,polymers,single crystal,3d frameworks,spin-crossover

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