HFO-1234yf as a CF3-building block: Synthesis of trifluoromethyl-benzophenone derivatives by deoxygenative aromatisation
Journal of Fluorine Chemistry（2021）
Abstract
•Trifluoromethyl ynones are derived from refrigerant 2,3,3,3-tetrafluoropropene (HFO-1234yf).•Diels-Alder reactions of trifluoromethyl ynones with furans occur.•Deoxygenation of oxabicyclic adducts give ortho-trifluoromethyl benzophenone products.
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Key words
Trifluoromethyl ynone,HFO-1234yf,Trifluoromethyl benzophenone,Aromatisation,Cycloaddition
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