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Inorganic salt hydrates and zeolites composites studies for thermochemical heat storage

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS(2021)

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Abstract
Salt hydrates (MgSO4 and ZnSO4) impregnated in zeolites, offer a variety of improvements, mostly providing a large surface area for salt hydrates and water molecules. A composite of 5 and 10% of salt contents were prepared as heat storage materials. The study's finding showed that dehydration enthalpy of MgSO4 (1817 J g(-1)) and ZnSO4 (1586 J g(-1)) were 10 and 15% improved than pure salt hydrates by making composites. During the hydration process of composites, the water sorption is 30-37% improved and further the increasing of salt contents in composites enhances more 10% increase in the water resorption. The cyclicability of MgSO4/zeolite and ZnSO4/zeolite were 45 and 51% improved than their corresponding pure salt hydrates. The effect of humidity on the water sorption result reveals that composites of MgSO4/zeolite and ZnSO4/zeolite at 75% relative humidity (RH), the mass of water are 51 and 40% increase than 55% RH.
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Key words
energy storage, renewable resources, salt hydrate, thermal properties, zeolites
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