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Photoresponsive Dynamic Covalent Bond Based On Addition-Fragmentation Chain Transfer Of Allyl Selenides

POLYMER CHEMISTRY(2021)

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摘要
A new dynamic C-Se bond-based addition-fragmentation chain transfer (AFCT) reaction of allyl selenides was performed under irradiation without any catalyst. ESR data and theoretical results indicated that the transfer reaction proceeded through a radical mechanism. This new dynamic bond holds great potential for application in smart polymer materials.
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关键词
photoresponsive dynamic covalent bond,allyl selenides,addition–fragmentation chain transfer
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