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Green preparation of carbon dots from Momordica charantia L. for rapid and effective sensing of p-aminoazobenzene in environmental samples

Yongli Liu,Xiaoyan Su,Letian Chen,Huanjia Liu, Chunyuan Zhang, Jiali Liu, Jiayi Hao, Yu Shangguan,Guifen Zhu

Environmental Research(2021)

Cited 12|Views15
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Abstract
p-Aminoazobenzene (pAAB) is a hazardous azo dye that causes considerable harm to human health and the environment. The development of novel and sensitive sensors for the rapid detection of pAAB is in high demand. In this study, a simple fluorescent sensor for pAAB detection is designed based on carbon dots (CDs) which are prepared using green carbon source of Momordica charantia L. via a facile hydrothermal approach. The fluorescence spectra of CDs exhibit considerable overlap with the absorption band of pAAB, and the fluorescence is specifically suppressed in the presence of pAAB ascribed to the inner filter effect. Good and wide linearity is observed in the pAAB concentration range of 0.01–12.5 μg mL−1 with a lower detection limit of 3.9 ng mL−1. The established method achieves good results with a rapid analysis of pAAB in different practical water and soil samples. The as-constructed fluorescent sensor provides a simple, rapid, economical and eco-friendly platform and possesses prospective applications for the effective, selective and sensitive detection of pAAB in the environmental field.
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Key words
Carbon dots,p-Aminoazobenzene,Fluorescence quenching,Inner filter effect
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