Nickel(Ii)- And Silver(I)-Catalyzed C-H Bond Halogenation Of Anilides And Carbamates
SYNTHESIS-STUTTGART(2021)
Abstract
ortho-C-H bond halogenation of anilides and N-aryl carbamates using easily available N-halosuccinimides (NXS) as the active halogenation reagent in the presence of nickel or silver catalyst has been developed. This method provides a new approach to 2-haloanilides and carbamates, which may serve as starting materials for the synthesis of pharmaceutically and biologically active compounds.
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Key words
cross-coupling reactions, C-H activation, homogeneous catalysis, halogenation, nickel, silver
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