Design and Application of Indole‐Based Allylic Donors for Pd‐Catalyzed Decarboxylative Allylation Reactions
Chinese Journal of Chemistry(2020)
摘要
The Summary of main observation and conclusion A new class of indole-based allylic donors have been designed and developed for palladium-catalyzed decarboxylative allylations. In addition, the first application of these indole-based allylic donors in palladium-catalyzed decarboxylative [3+2] cycloaddition and allylic amination has been achieved by reacting with isocyanates and sulfonyl amines, respectively. This approach represents the first design of indole-based allylic donors, which is helpful for settling the challenge of designing and developing new class of heterocycle-based allylic donors for Pd-catalyzed decarboxylative allylation reactions. Moreover, the application of this new class of allylic donors in cycloadditions and substitutions will add new contents to the research field of decarboxylative allylation.
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关键词
Allylic compounds, Allylation, Indole, Cycloaddition, Substitution
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