Copper-Catalyzed N-H Insertion Reactions From Sulfoxonium Ylides
TETRAHEDRON（2020）
Abstract
The first use of copper(II) as an efficient catalyst for N-H insertion reactions between anilines and alpha-carbonyl sulfoxonium ylides is described. Products, 39 arylglycine derivatives, were obtained in yields up to 97% employing a simple and fast experimental procedure. (C) 2020 Elsevier Ltd. All rights reserved.
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Key words
Sulfoxonium ylides, N-H insertion, Metal-carbene, Arylglycine derivatives, Copper catalysis
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