Light-Emitting Metal-Organic Halide 1D and 2D Structures: Near-Unity Quantum Efficiency, Low-Loss Optical Waveguide and Highly Polarized Emission
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION(2021)
Abstract
Organic-inorganic metal-halide materials (OIMMs) with zero-dimensional (0D) structures offer useful optical properties with a wide range of applications. However, successful examples of 0D structural OIMMs with well-defined optical performance at the micro-/nanometer scale are limited. We prepared one-dimensional (1D) (DTA)(2)SbCl5.DTAC (DTAC=dodecyl trimethyl ammonium chloride) single-crystal microrods and 2D microplates with a 0D structure in which individual (SbCl5)(2-) quadrangular units are completely isolated and surrounded by the organic cation DTA(+). The organic molecular unit with a long alkyl chain (C-12) and three methyl groups enables microrod and -plate formation. The single-crystal microrods/-plates exhibit a broadband orange emission peak at 610 nm with a photoluminescence quantum yield (PLQY) of ca. 90 % and a large Stokes shift of 260 nm under photoexcitation. The broad emission originates from self-trapping excitons. Spatially resolved PL spectra confirm that these microrods exhibit an optical waveguide effect with a low loss coefficient (0.0019 dB mu m(-1)) during propagation, and linear polarized photoemission with a polarization contrast (0.57).
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Key words
optical waveguides,organic–,inorganic metal-halide materials,polarized emission,quantum efficiency,zero-dimensional structure
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