Carbon nanomaterials treated by combination of oxidation and flash for highly efficient solar water evaporation.

The high-efficiency solar evaporation is a potential technique to desalinate hypersaline wastewater and seawater to alleviate the global fresh water shortage. Photo-thermal agent and solar evaporator with low-cost raw materials, high photo-thermal conversion efficiency and simple-fast preparation methods is crucial to realize the industrial application of solar evaporation. Herein, carbon nanomaterial with higher light absorption and photo-thermal conversion efficiency than that of carbon black was obtained by combination treatment of carbon black with oxidation and flash illumination. In order to characterize the evaporation performance of the devices, a floating evaporator was fabricated with the carbon nanomaterial on the top of polyethylene foam wrapped with non-woven fabrics. The evaporation rate and photo-thermal conversion efficiency of evaporators were affected significantly by environmental temperature and humidity. At the environmental temperature of 19.5 °C, the evaporator fabricated with the combined treated carbon nanomaterial as photo-thermal agents presents a stable evaporation rate at 1.27 kg m-2 h-1 and solar evaporation efficiency at 78.7% under 1 kW m-2 simulated sun illumination, which are higher than those of evaporator with carbon black (1.13 kg m-2 h-1 and 68.1%). The distilled water obtained from the solar evaporator met the standards of drinkable water. Overall, the experimental result demonstrates a great promise application of treated carbon nanomaterial as a photo-thermal agent in the field of seawater desalination and solar-energy collector.