All Slot-Die Coated Non-Fullerene Organic Solar Cells With Pce 11%

Slot-die (SD) coating is used to fabricate fully solution processed organic solar cells (OSCs) based on a blend of high performance donor polymer (PTB7-Th) and a non-fullerene acceptor (IEICO-4F) for stable devices over extended periods of operation. The optimization of a sequential deposition process of transport and active layers, under ambient conditions, enable high efficiency slot-die coated solar cells with remarkable power conversion efficiencies (PCE) > 11.0% to bridge the gap between lab-to-fab. Fully slot-die coated inverted OSCs are demonstrated with efficiencies reaching 11% along with 1 cm(2) devices, proving the scalability and reproducibility of the proposed technique. Further, replacing the evaporated Ag electrode with solution processed Ag nanowire (AgNW) electrodes shows the highest light utilization efficiency of 5.26% for semi-transparent OSC with a PCE of 9.07% and average visible transmission of 58%.