Pvdf-Hfp/Nkbt Composite Dielectrics: Perovskite Particles Induce The Appearance Of An Additional Dielectric Relaxation Process In Ferroelectric Polymer Matrix

Na0.25K0.25Bi0.5TiO3 (NKBT) perovskite particles are synthesized by solid-state method and used as a filler for polyvinylidene fluoride-co-hexafluoropropylene (PVDF-HFP) co-polymer. X-ray diffraction analysis of NKBT powders shows that the particles have a rhombohedral perovskite crystal structure (R3c symmetry). Raman spectroscopy reveals that the co-polymer crystallizes predominantly into the mixture of polar beta- and gamma-crystals, while there is also a contribution of the non-polar a-crystal phase. The introduction of the NKBT into the PVDF-HFP results with an increase in effective dielectric permittivity and this effect depends on the inorganic content in the composite. The most interesting result of the present study is that the introduction of NKBT particles induces the appearance of an additional transition peak in the dielectric spectra of the co-polymer matrix. At the fixed frequency of similar to 2 kHz, the observed process appears at similar to 10 degrees C (about 45 degrees above the glass transition temperature) and its magnitude strongly depends on the amount of the NKBT in the composite. Dielectric spectroscopy measurements of the composites are carried out in the wide range of frequencies (from 0.1 Hz to 1 MHz) and temperatures (from -100 to 100 degrees C). They reveal that the novel process can be clearly distinguished in the frequency range between 160 Hz and similar to 50 kHz.