Physicochemical study on molecular interactions of ternary aqueous solution containing ionic liquid 1-octyl-1-methylpyrrolidinium bromide and amino acid/glycyl dipeptide at various temperatures
The Journal of Chemical Thermodynamics(2021)
Abstract
•Addition of small biomolecule in water decreases the cmc and Nagg of [C8C1Pyrr]Br.•Thermodynamic parameters of micellization of [C8C1Pyrr]Br have been obtained.•The hydrophilic-hydrophilic interactions between [C8C1Pyrr]Br and amino acids/glycyl dipeptides are dominant.•Increase in concentration and alkyl chain length enhances the affinity between biomolecule and [C8C1Pyrr]Br.
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Key words
1-Octyl-1-methylpyrrolidinium bromide,Amino acid and glycyl dipeptide,Solute-solvent interaction,Thermodynamic parameters
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