Vibrational spectra of La@C60 and Ce@C60 endohedral fullerenes: Influence of spin state multiplicity

S. Civiš,A.V. Krisilov,M. Ferus,I.V. Nechaev,P. Kubelík,V.E. Chernov,B.A. Zon

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY（2021）

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摘要

•Endohedral fullerenes with paramagnetic encapsulated atoms are new magnetic materials.•They have new vibrational frequencies not associated with empty fullerenes.•The vibrational spectrum depends considerably on the encapsulated atom’s spin state.

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关键词

Spin excited states,Infrared vibrational spectra,Endohedral metallofullerenes,Metal–cage vibration frequencies

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