己内酰胺与十二内酰胺共聚尼龙的合成

Journal of Hangzhou Normal University (Natural Sciences Edition)(2014)

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Abstract
通过阴离子开环聚合的方法制备了共聚尼龙6-12.TGA 分析结果显示随着十二内酰胺的加入尼龙的热稳定性增强;DSC分析结果表明十二内酰胺的加入使得尼龙链段的混乱度增加,氢键密度减少,结晶度下降;同时共聚物红外谱图中-NH的特征峰出现红移.
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Key words
nylon 6-12 copolymer,caprolactam,laurolactam,anionic polymerization
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