基于吉布斯弯曲界面相平衡判据的开尔文方程推导

University Chemistry(2016)

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Abstract
对两种界面热力学处理方法(古根海姆法与吉布斯法)进行了介绍.采用吉布斯界面热力学方法建立了存在界面相时两相平衡的热力学判据,并以此为基础提出了一种新的开尔文方程推导方法.
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Key words
kelvin equation,phase equilibrium,curved interface
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