叔丁基二苯基氢硅烷的合成方法研究
Chemical Research and Application(2017)
Abstract
以叔丁基二苯基氯硅烷(SCl)为原料,硼氢化钾/氯化锌(KBH4/ZnCl2)为还原体系,制备了叔丁基二苯基氢硅烷(SH),产物结构经1 H-NMR确证.通过单因素、正交实验和放大重复性实验确定了最佳反应条件为n(KBH4):n(ZnCl2):n(SCl)为2:1.25:1,100℃反应18h,平均收率为93.7%.该法具有原料易得,反应温和,操作方便,收率高,对环境友好等优点,适合工业化生产.
MoreTranslated text
Key words
t-butyldiphenylsilane,t-butylchlorodiphenylsilyl,potassium borohydride,zinc chloride,reduction
AI Read Science
Must-Reading Tree
Example
![](https://originalfileserver.aminer.cn/sys/aminer/pubs/mrt_preview.jpeg)
Generate MRT to find the research sequence of this paper
Chat Paper
Summary is being generated by the instructions you defined