化合物Zn2(H2PO4)2(HPO4)2·2C5H9N2的离子热合成及表征

Journal of Molecular Science(2015)

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Abstract
以碘化1,3-二甲基咪唑离子液体为溶剂,在离子热条件下,合成了二维磷酸锌Zn2(H2PO4)2(HPO4)2·2C5H9N2.结果证实,该化合物属单斜晶系,为P21/n空间群,晶胞参数为a=1.336 2(10) nm,b=1.037 4(10) nm,c=1.780 9(13) nm,β=97.194 0(10).,V=2.449 2(3) nm3,Z=4.
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Key words
zinc phosphate,3-dimethyl imidazolium iodide,ionothermal synthesis,ionic liquid,hydrogen bond
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