长链卟啉金属配合物的合成与性质研究

Er-jun SUN,Shan-shan WANG,Xiao-yan BAI,Guo-jian SUN,Li Tian

Chinese Journal of Synthetic Chemistry（2020）

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Abstract

通过带有12条长链的卟啉配体meso-5,10,15,20-四[3,4,5-三(辛酰氧基)苯基]卟啉(P),与金属氯化盐(ZnCl2,CuCl2,CoCl2,NiCl2,CdCl2,MnCl2,PdCl2和PtCl2)发生配位反应,合成出长链卟啉的8种金属配合物:Zn-P,Cu-P,Co-P,Ni-P,Cd-P,Mn-P,Pd-P和Pt-P,结构性质经UV-Vis,1 H NMR,IR和HR-MS(ESI)表征.

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