地层水有机酸热演化动态、定量预测模型及应用

Petroleum Geology & Oilfield Development in Daqing(2015)

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Abstract
为了建立地层水有机酸热演化动态、定量预测模型,在深入分析乙酸钠水溶液热解实验结果、实验条件、反应机理之间关系的基础上,采用优化计算方法,建立了动态、定量预测地层水有机酸热演化的化学动力学模型.研究表明:单分子脱羧反应是地质条件下地层水有机酸热解的主要反应途径;乙酸根单分子脱羧反应活化能为182.46 kJ/mol-1,指前因子为3.10×109s-1;经对大庆长垣西地区泉四段实际验证,所建模型适于地质条件下地层水.
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Key words
organic-acid thermal evolution,kinetic model,prediction,formation water,Daqing Placanticline
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