Hydrodesulfurization of dibenzothiophene and its hydrogenated intermediates over bulk CoP and Co2P catalysts with stoichiometric P/Co ratios
Journal of Catalysis(2021)
Abstract
•CoP and Co2P were prepared with stoichiometric P/Co ratios.•Hydrodesulfurization (HDS) reactions over CoP and Co2P followed different kinetics.•CoP was much more active and more nitrogen-tolerant than Co2P.•The network of the HDS of dibenzothiophene over CoP and Co2P was determined.•The cobalt phosphosulfide phases were formed in the HDS reactions.
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Key words
Hydrodesulfurization,Dibenzothiophene,Hydrogenated intermediates,CoP,Co2P,Piperidine
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