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PCL/SiOx复合膜的热学、力学及阻隔性能

齐小晶,宋树鑫,梁敏,刘林林,张玉琴,云雪艳,王羽,董同力嘎

China Plastics Industry（2015）

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Abstract
利用等离子体增强化学气相沉积(PECVD)法制备聚己内酯(PCL)/氧化硅(SiOx)复合膜,研究了SiOx镀膜时间对PCL热学、力学及阻隔性能的影响.结果表明,随着镀膜时间的延长复合膜阻隔性提高;测试温度为25℃时,PCL和PCL/SiOx(60 min)薄膜的氧气透过率分别为1 868和1 123 cm3/(m2· 24h),水蒸气透过率分别为92.1和81.1 g/(m2· 24h),其热学和力学性能几乎保持原有PCL的性能,蒸镀SiOx可提高PCL对氧气和水蒸气的阻隔性.
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