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新颖的稀土镨羧酸配合物的性质研究

Yunjing Hao,Lingyan Zhao, Ning Wang,Pingping Ma,Shanshan Fu

Coal and Chemical Industry（2018）

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Abstract
水热法合成了一个新颖稀土镨和对氯苯氧乙酸(PCPA)的配合物[Pr (PCPA)3(H2O)]n.对氯苯氧乙酸中的羧基以2种不同的配位方式与镨配位,最终形成了一维链状结构.对配合物的热重分析表明此配合物具有很好的稳定性,量化计算的结果与配合物的配位情况一致.
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