Preparation Of Nanoparticle Porous-Structured Bivo4 Photoanodes By A New Two-Step Electrochemical Deposition Method For Water Splitting
CATALYSTS(2021)
摘要
In the synthesis method of a BiVO4 photoanode via BiOI flakes, a BiOI film is formed by electrochemical deposition in Step 1, and a vanadium (V) source solution is placed by drop-casting on the BiOI film in Step 2. Following this, BiVO4 particles are converted from the BiOI-(V species) precursors by annealing. However, it is challenging to evenly distribute vanadium species among the BiOI flakes. As a result, the conversion reaction to form BiVO4 does not proceed simultaneously and uniformly. To address this limitation, in Step 2, we developed a new electrochemical deposition method that allowed the even distribution of V2O5 among Bi-O-I flakes to enhance the conversion reaction uniformly. Furthermore, when lactic acid was added to the electrodeposition bath solution, BiVO4 crystals with an increased (040) peak intensity of the X-ray diffractometer (XRD) pattern were obtained. The photocurrent of the BiVO4 photoanode was 2.2 mA/cm(2) at 1.23 V vs. reversible hydrogen electrode (RHE) under solar simulated light of 100 mW/cm(2) illumination. The Faradaic efficiency of oxygen evolution was close to 100%. In addition, overall water splitting was performed using a Ru/SrTiO3:Rh-BiVO4 photocatalyst sheet prepared by the BiVO4 synthesis method. The corresponding hydrogen and oxygen were produced in a 2:1 stoichiometric ratio under visible light irradiation.
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关键词
bismuth vanadate photoanode, electrochemical deposition, nanoparticle porous structure, water splitting, strontium titanate photocatalyst sheet
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