Facile Preparation Of High-Performance Spinel Limn2-Xcuxo4 Cathodes By Microwave-Induced Solution Flameless Combustion

A series of LiMn2-xCuxO4 (0 <= x <= 0.1) cathode materials were synthesized via a rapid microwave-induced solution flameless combustion technique, and the structure, morphology and electrochemical performances of the LiMn2-xCuxO4 samples were investigated in detail. All the as-prepared samples are the single crystal materials with a high crystallinity and correspond to the well-defined spinel structure. The spinel structure stability is effectively improved by the appropriate Cu-doping that is conducive to increasing the average valence of Mn and reducing lattice parameter. Consequently, the optimized LiMin(1.)(925)Cu(0.)(075)O(4) sample delivers a first discharge specific capacity of 108.5 mAh g(-1) at 1 C and achieves the long-term charge/discharge cycle of 1000 cycles. At high current rate of 5 degrees C and 10 C after 1000 cycles, the capacity retention of over 61% can be maintained. Even at the elevated temperature of 55 degrees C, the high initial capacity of 111.4 mAh g(-1) and capacity retention of 63.91% are also delivered after 100 cycles at 1 degrees C. This is ascribed to the favorable Li+ diffusion kinetics, low charge transfer resistance and apparent activation energy.