The Evolution Of Saponite: An Experimental Study Based On Crystal Chemistry And Crystal Growth

Element incorporation and partitioning during the evolution of clay minerals have significant implications for element cycling in geochemical processes. The main aim of this experimental study is to further our understanding of element redistribution and crystal growth during smectite evolution under different physicochemical conditions. The precursors (i.e., pure Mg- and Ni-saponite) were separately prepared by hydrothermal syntheses at the same set of temperatures (i.e., RT, 50, 150, 180, 200, and 220 degrees C) for one day. Then the starting materials were obtained from the mechanical mixtures of the identical molar weight of Mg- and Ni-smectite precursors prepared at the same temperature. Subsequently, Series I samples were obtained by hydrothermally treating different starting materials at 220 degrees C for two weeks while Series II samples were hydrothermally synthesized under various temperatures (220, 300, 400, and 500 degrees C) for one week using the starting materials prepared at 220 degrees C. Both the precursors and resultant saponites were characterized by XRD, FTIR, TEM, and STEM. The FTIR spectra of the precursors only exhibit the nu Mg3OH and nu Ni3OH bands, corresponding to Mg-saponite and Ni-saponite, respectively. However, the occurrence of nu Mg2NiOH and nu Ni2MgOH bands in the resultant saponite indicates the dissolution of the corresponding Mg- and Ni-saponite precursors and recrystallization of Mg-Ni mixed saponite. The dissolution extents of Mg- and Ni-saponite precursors, which affect the degrees of random distribution of octahedral Ni and Mg in resultant Mg,Nisaponite, are significantly controlled by the temperature gap (Delta T) between the precursors prepared and the resultant Mg,Ni-saponite obtained. In general, a larger Delta T leads to a higher dissolution extent of saponite precursors and a higher degree of random distribution of octahedral Ni and Mg cations in the resultant Mg,Ni-saponite structures. Thus, the distribution mode of octahedral cations in saponite, which is not only relevant to a given hydrothermal temperature but also dependent on Delta T for final products, cannot be used as a geothermometer. TEM and STEM observations provide visual evidence that the particles of saponite coarsen when Delta T is higher than zero. Both the crystal-chemical and morphological features during saponite evolution suggest that saponite particles coarsen mainly via partial/complete dissolution of precursors followed by recrystallization and growth of Mg,Ni-saponite in which crystal growth by layer attachment cannot be excluded. This study presents an experimental approach to evaluate the evolution of clay minerals in terms of crystal chemistry and crystal growth and offers a better understanding of the contributions of clay mineral evolution to element cycling.