Metal substitution effects of aluminophosphate AlPO4-5 as solid acid catalyst for esterification of acetic acid with ethanol
Molecular Catalysis(2021)
摘要
•Metal substitution on AlPO4-5 catalysts explored for ethanol esterification.•Metal incorporation affected morphology, pore merits, and active sites.•Concentration and strength of acid sites and mass transfer effects were tuned.•Si and Co substituted AlPO4-5 were the most active analogues for the esterification.•Optimized SAPO-5 exhibited comparable performance to commercial Zeolite β.
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关键词
Esterification,Aluminophosphates,Ethanol,Acetic acid,Conversion,Ester,Solid acid catalysts,SAPO-5,Acidity
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