Preparation method of zinc oxide-metal organic framework composite antibacterial material

user-5f8411ab4c775e9685ff56d3(2020)

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摘要
The invention relates to a preparation method of a zinc oxide-metal organic framework composite antibacterial material. Lanthanide-series MOFs which are good in biological property and easy to prepareare adopted as a framework material; the MOFs-Ln is prepared from thiodiacetic acid (TDA) and lanthanide nitrate. Through two-step stripping, the particle sizes and porosity of the MOFs-Ln can be adjusted, so MOFs structures of different sizes are obtained; and then, zinc nitrate, sodium hydroxide and sodium chloride are used for growing ZnO NPs on the surface and in pores of the MOFs-Ln in an in-situ growth mode, so the ZnO NPs@MOFs-Ln material with good antibacterial performance can be obtained. The morphology and particle size of MOFs-Ln can be regulated and controlled by changing the content and reaction time of TDA and lanthanide nitrate and changing a stripping mode, so the subsequent growth size of ZnO NPs is influenced, and the generation of nanoscale ZnO particles with high antibacterial activity is limited; and the material has efficient antibacterial effects.
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关键词
Zinc nitrate,Particle size,Zinc,Sodium hydroxide,Antibacterial activity,Particle,Composite number,Metal-organic framework,Chemical engineering,Materials science
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