Formation Of A Tris(Catecholato) Iron(Iii) Complex With A Nature-Inspired Cyclic Peptoid Ligand
DALTON TRANSACTIONS(2021)
Abstract
Siderophore-mimicking macrocyclic peptoids were synthesized. Peptoid 3 with intramolecular hydrogen bonds showed an optimally arranged primary coordination sphere leading to a stable catecholate-iron complex. The tris(catecholato) structure of 3-Fe(iii) was determined with UV-vis, fluorescence, and EPR spectroscopies and DFT calculations. The iron binding affinity was comparable to that of deferoxamine, with enhanced stability upon air exposure.
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Key words
cyclic peptoid ligand,iron<scp>iii</scp>,nature-inspired
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