Light-Driven Hydrogen Production With Cdse Quantum Dots And A Cobalt Glutathione Catalyst

Rebeckah Burke,Saikat Chakraborty,Kevin P McClelland,Jana Jelušić,Ellen M Matson,Kara L Bren,Todd D Krauss

CHEMICAL COMMUNICATIONS（2021）

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摘要

A photocatalytic hydrogen (H-2) production system is reported using glutathione (GSH)-capped CdSe QDs with a cobalt precatalyst, yielding 130 000 mol H-2 per mol cobalt over 48 hours. Analysis of the reaction mixtures after catalysis indicates that the active catalyst is a labile complex of cobalt and GSH formed in situ.

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关键词

Electrocatalytic Hydrogen Production,Photocatalysts,Hydrogen Production,Photosynthetic Systems

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