Charge Transfer Parameters Of Nixmnyco1-X-Y Cathodes Evaluated By A Transmission Line Modeling Approach
Energy technology(2021)
摘要
The performance of lithium-ion batteries can be analyzed and improved by appropriate electrochemical models. A challenging yet crucial part is the parameterization of these models. Until now, the literature has incompletely investigated and cited the charge transfer process parameters describing the lithium transfer between the active material particles in the electrode and the liquid electrolyte. Herein, a novel approach is presented for obtaining these charge transfer parameters. The well-established experimental methods of electrochemical impedance spectroscopy and focused ion beam tomography are applied. By introducing both experimental results into a transmission line model, a reliable determination of the charge transfer parameters j(0), k, and r(CT) can be achieved. The new approach is validated by comparing the results of four cathodes, all containing the state-of-the-art active material NixMnyCo1-x-y (NMC), but with different microstructures and/or stoichiometries.
更多查看译文
关键词
charge transfer kinetics, electrochemical modeling, exchange current density, focused ion beam tomography, lithium-ion cathodes, transmission line models
AI 理解论文
溯源树
样例
![](https://originalfileserver.aminer.cn/sys/aminer/pubs/mrt_preview.jpeg)
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要