The study on nanostructural evolution of CuO/Graphene oxide nanocomposite during the first discharge processes
Materials Chemistry and Physics(2021)
摘要
Nanostructure of CuO plays a critical role in Li-ion battery (LIB) applications of CuO/graphene oxide (GO) nanocomposites. Morphological evolution of CuO/GO anode material provides essential information for developing the performance of LIBs. But, the nanostructural evolution of the CuO/GO anode materials have not been previously studied by in situ electrochemical-synchrotron radiation techniques. In this paper, different CuO morphology in preparation of CuO/GO nanocomposites could be controlled by increasing the reactive time at 83 °C. In situ synchrotron X-ray diffraction and small angle X-ray scattering (SAXS) are employed to characterize the structural behavior of CuO/GO samples during the first cycle. The CuO(-511) Bragg peak demonstrates a more significant shift toward higher angles due to the incorporation of Li+ in the CuO crystal lattice. SAXS indicates that the formation and growth of SEI are observed with lithiation dose, and subsequently some cracks occur. The in situ electrochemical-synchrotron techniques could be implemented to help further understand the electrochemical behaviors and conversion mechanism of anode materials.
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关键词
Synchrotron radiation,X-ray technique,Copper oxide,Nanostructure,Anode material
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