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Interfacial Processes-The Key Steps of Phase Transfer Catalyzed Reactions

Mieczyslaw Makosza,Michal Fedorynski

CATALYSTS（2020）

Cited 15|Views0
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Abstract
After short historical introduction, interfacial mechanism of phase transfer catalyzed (PTC) reactions of organic anions, induced by aqueous NaOH or KOH in two-phase systems is formulated. Subsequently experimental evidence that supports the interfacial deprotonation as the key initial step of these reactions is presented.
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Key words
carbanions,dichlorocarbene,sodium hydroxide,interfacial processes,quaternary ammonium salts,phase transfer catalysis,alkylation
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