Interface-coupling in FeOOH/MXene Heterojunction for Highly Reversible Lithium-ion Storage

ABSTRACT Recently, MXene coupling with active nanomaterials show considerable potential for energy storage applications. However, the complicated fabrication of MXene based composites and their low Li+ storage reversibility impede the further application for lithium-ion batteries. Herein, as a proof of concept, a novel architecture of β-FeOOH quantum dots grafted on Ti3C2 flakes has been realized via a one-step facile immersion method. The crumple Ti3C2 MXene in the synthetic hybrids functions as a favorable matrix to load FeOOH dots due to its open framework, superior electrical conductivity and low energy barrier of Li+ diffusion. In virtue of the strong interfacial interactions of the formed heterojunctions between alkali-Ti3C2 matrix and FeOOH, the hybrid enables the enhanced kinetics of charge transfer and stable interfacial structure. Consequently, the FeOOH@3D-MX electrode exhibits superior high-rate capability (286.1 mAh g-1 at 10 A g-1) and particularly durable lithium-ion storage with no capacity decay over 500 cycles (572.3 mAh g-1 after 500 cycles at 500 mA g-1). The enhanced Li+ storage mechanism of FeOOH/MXene heterostructures is also evidenced by density functional theory calculations and kinetics analyses. This work exploits a facile strategy to build high-performance anode composite and paves the way to exploring their energy storage mechanisms.