Stability of Zeolite HZSM-5 in Liquid Phase Dehydration of Methanol to Dimethyl Ether

CATALYSIS LETTERS(2020)

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摘要
A high performance HZSM-5 catalyst for liquid phase dehydration of methanol to dimethyl ether (DME) was developed by optimizing Si/Al ratio and hydrothermal treatment temperature. During 6788 h long term test, DME selectivity kept above 99.96% and only slight deactivation was observed primarily due to coking and decline of HZSM-5 crystallinity. Graphic Abstract
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关键词
Dimethyl ether, Liquid phase dehydration, ZSM-5, Deactivation, Dissolution
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