Time-resolved Infrared Characterization on the Photolysis of Roussin's Red Phenyl Ester in Different Solvents
Journal of Photochemistry and Photobiology A: Chemistry（2021）
Abstract
The 355-nm nanosecond pulsed laser was employed to initiate the photolysis of Roussin's red benzyl ester, Fe2(μ-SPh)2(NO)4, in different solvent compositions. Cyclohexane serves as a weakly interactive medium to solvate the photointermediate; THF and DX coordinate to the vacancy of the photointermediate via lone pair electrons.
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Key words
Coordination,Solvation,Photolysis,Roussin's red phenyl ester,Step-scan time-resolved infrared interferometer
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