Non-Markovian Models Of The Growth Of A Polymer Chain

D. Sokolovski,S. Rusconi, E. Akhnnatskaya, J. M. Asua

PROCEEDINGS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES(2015)

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Abstract
Using simple exactly solvable models, we show that event-dependent time delays may lead to significant non-Poisson effects in the statistics of polymer chain growth. The results are confirmed by stochastic simulation of various growth scenarios. Our interest in mathematical aspects of non-Markovian growth arises from recent successful application of delayed probability density functions in stochastic modelling of controlled radical polymerization.
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Key words
non-Markovian growth,event-dependent delays,polymerization
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