Synthesis and crystal structure of rare-earth biuret complexes with linear pentaiodide ions: Infinite polyiodide chains in a cationic framework
Journal of Molecular Structure(2021)
Abstract
•Linear pentaiodide ion can be described as two I2 molecules attached to the central I–.•Pentaiodide-ions fill channels of 3-D framework of complex cations and iodide ions.•The structure resembles iodine–starch complex.•The polarizability is maximal along polyiodide chain.•Electronic conductivity along polyiodide chain can be assumed.
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Key words
Rare-earth complex,Biuret,Polyiodides,X-ray diffraction,Theoretical calculations,Starch-iodine complex
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