Re(V) complexes containing the phenylimido (NPh2−) core and SNS-thiosemicarbazide ligands

Alice P. Borges,Bruna Possato,Adelheid Hagenbach,Antonio E. H. Machado,Victor M. Deflon,Ulrich Abram,Pedro I. S. Maia

Inorganica Chimica Acta（2021）

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摘要

•Thiosemicarbazonate complexes containing the (ReNPh)3+ core have been successfully prepared.•Three complexes were studied by single-crystal X-ray diffraction.•A “3 + 2” mixed-ligand complex was obtained in order to completely envelope the metal center.•A prototype compound with potential for couplings to biomolecules was designed by means of DFT calculation.

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关键词

Rhenium complexes,Technetium complexes,Radiophamaceuticals,Anticancer drugs,Biocoupling

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