Studies on Interactions of 5,6-Diaryl-3-(Quinolin-2-YL)-1,2,4-Triazines with Arynes: A TM-Free One-Step Approach to 2-(3,4-Diarylisoquinolin-1-YL)Quinolines

Sravya Gundala,Albert F. Khasanov,Dmitry S. Kopchuk,Ekaterina S. Starnoskaya,Yaroslav K. Shtaitz,Alexey P. Krinochkin,Eugeny B. Gorbunov,Grigory V. Zyryanov,Venkatapuram Padmavathi,Oleg N. Chupakhin

POLYCYCLIC AROMATIC COMPOUNDS（2022）

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Abstract

Interactions of 5,6-diaryl-3-(quinolin-2-yl)-1,2,4-triazines with arynes are studied. 2-(3,4-Diarylisoqunolin-1-yl)quinolines are obtained in up to 65% yieldviathe inverse-demand Diels-Alder reaction between 5,6-diaryl-3-(quinolone-2-yl)-1,2,4-triazines and benzyne, generatedin situ.

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Key words

Diels-Alder reaction, quinolones, triazines, in situreaction

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