Kinetics of the reductive amination of 1-undecanal in thermomorphic multicomponent system

Chemical Engineering Science(2021)

引用 14|浏览12
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摘要
•Transformation of an aldehyde from sustainable sources into a tertiary amine.•Kinetic description of the reductive amination of a long chain aldehyde.•Water influence on aldehyde-enamine equilibrium mathematically described.•Quantum chemical calculations deliver accurate thermodynamic and kinetic parameters.•Fundamental basis for a kinetic description of the hydroaminomethylation.
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关键词
Homogeneous rhodium catalysis,Reductive amination,Reaction kinetics,Computational chemistry,Kinetic modelling
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