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Total synthesis of agastaquinone, a diterpenoid quinone isolated fromAgastache rugosa

Sangku Lee,Jisu Yoo,Jae-Kyung Jung,Jae Nyoung Kim,Myeong Sik Yoon

SYNTHETIC COMMUNICATIONS（2021）

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Abstract
Agastaquinone is a tricyclic diterpenoid isolated fromAgastache rugose. The first total synthesis of agastaquinone was accomplished based on intramolecular Friedel-Crafts acylation of aryl lactone followed by aromatization leading to the tricyclic phenol core structure as a key step.
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Key words
Friedel-Crafts acylation,diterpenoid,quinone,total synthesis
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