Unexpected Discovery of Magnesium-Vanadium Spinel Oxide Containing Extractable Mg2+ As a High-Capacity Cathode Material for Magnesium Ion Batteries
CHEMICAL ENGINEERING JOURNAL(2021)
Abstract
Magnesium ion batteries (MIBs) have attracted significant attention as a promising candidate for the next generation energy storage system owing to their large volumetric capacity and abundant resource. Currently, several researchers have focused on Mg-free materials to be used as cathode in MIBs; But the exploration of Mg-rich electrode materials will promote the development of magnesium batteries towards obtaining more flexible MIBs. Herein, a Mg(Mg0.5V1.5)O-4 is investigated as a potential cathode material, in which the Mg2+ can be extracted and the fast Mg2+ reaction kinetics. Benefited from the exceptional cathode, the Mg battery shows a high reversible specific capacity of 250 mA h g1 at 100 mA g(1) and capacity retention of 100 mA h g1 after 500 cycles at high rate of 1 A g(-1). The excellent rate capability and desirable cycling performance obtained herein outperformed those of previously reported magnesium spinel oxides. It is also demonstrated that Mg2+ extraction/insertion mechanism of Mg(Mg0.5V1.5)O-4 is related to the coexistence of two-phase process and single-phase solid solution reaction through a series of systematic in situ/ex situ characterizations. X-ray absorption near edge structure (XANES) demonstrates that the valence state of vanadium changes and the octahedral symmetry of vanadium site varies due to the extraction of Mg2+ from spinel Mg(Mg0.5V1.5)O-4. Significantly, the cathode containing extractable Mg2+ can be coupled with Mg-free anode materials (Na2Ti3O7) to assemble a full cell in Mg(TFSI)(2)/acetonitrile electrolyte, displaying a discharge capacity of 102 mA h g(-1) after 100 cycles at 50 mA g(-1). The encouraging results show that the Mg(Mg0.5V1.5)O-4 is a promising electrode material, which paves ways for the development and further improvements of MIBs.
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Key words
Magnesium ion battery,Mg-rich material,Spinel oxide cathode,Mg2+ extraction/insertion
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