Structural and magnetic study of a new dinuclear SMM

Inorganic Chemistry Communications(2020)

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摘要
A new single molecular magnet Dy2(OAc)4(pan)2(H2O)2 (1, pan=1-(2-pyridylazo)-2-naphthol) has been prepared and characterized by the assembly of pan and dysprosium acetate, in respect to the versatile coordination ability of pan to the various central metal ions. The complex 1 exhibits magnetic property in respect to the central Dy ions, and magnetic measurement indicates significant single molecular magnet behavior with an effective energy barrier of 30 K.
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关键词
Dysprosium,Dinuclear,Structure,Single-molecule magnet
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