Simple Development Of Kelvin Probe Using A Pa Meter And Its Application To Study The Photocatalytic Activities Of Ag/Tio2 And Ag2o/Tio2 Coated Polyester Fabrics

APPLIED SURFACE SCIENCE(2021)

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Abstract
The Ag/TiO2 and Ag2O/TiO2 films were deposited by magnetron sputtering on the polyester fabrics. The Kelvin probe system was simply developed and used to investigate the photoelectric properties of Ag/TiO2 and Ag2O/TiO2 junctions. The measured work functions of the deposited Ag, Ag2O and TiO2 are 4.65 eV, 5.53 eV and 5.03 eV, respectively. Ag2O/TiO2 junction has a 0.12 eV larger EF difference than Ag/TiO2 junction, indicating that Ag2O/TiO2 junction has a higher ability of charge separation than Ag/TiO2 junction. The photocatalytic activities of samples towards RB solution under 365 nm UV light were investigated. The results show that the Ag/TiO2 and Ag2O/TiO2 coated polyester fabrics have a far better photocatalytic performance than TiO2 coated polyester fabrics. And the photocatalytic activity of Ag2O/TiO2 coated sample is prominently higher than that of Ag/TiO2 coated sample, which is attributed to the larger EF difference and the wider space charge region of Ag2O/TiO2 junction compared with that of Ag/TiO2 junction.
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Key words
Development of Kelvin probe, Heterojunction, Ag/TiO2, Ag2O/TiO2, Functionalized polyester fabrics
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