Preparation of graphene-like carbon attached porous silicon anode by magnesiothermic and nickel-catalyzed reduction reactions
IONICS(2020)
Abstract
For improving performance of silicon anode in lithium ion batteries, a two-step preparation method was applied for synthesis of silicon carbon powder. The first step was to prepare Si/Ni composite powder by magnesiothermic reduction reaction in which Tetraethoxysilane (TEOS) was silicon source and NiCl 2 ∙6H 2 O was nickel source. The second step was to prepare silicon carbon in which triethylene glycol was carbon source and reduced by nickel catalyzed reactions on the surface of Si/Ni composite particles. Strawberry-like porous silicon attached with graphene-like carbon was found in the sample of Si-C powder treated by 1 M FeCl 3 and 5 wt.% HF. Charge/discharge performance of anode materials were measured in button cells. The highest discharge specific capacity of Si-C powder can reach to 1275 mAh g −1 , but the cycle performance was not as good as Si/Ni composite powder. At the 50 th cycle, the discharge specific capacity of Si/Ni composite powders and Si-C powders were 415 mAh g −1 and 395 mAh g −1 , respectively.
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Key words
Silicon carbon anode,Lithium ion battery,Magnesiothermic reduction reaction,Nickel catalyzed reduction reaction,Silicon nickel composite material
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